Foam stabilization mechanism of core-shell particles: Insights from the gas-liquid interface theory

Zhengxiao Xu, Guangzhe Ding, Lei Tao, Wenyang Shi, Jiajia Bai, Faqiang Dang

Abstract view|39|times       PDF download|10|times

Abstract


To improve oil displacement efficiency under deep reservoir conditions, foam flooding technology represents a critical strategy through the establishment of a stable, long-lasting foam system. A central challenge in this application is to characterize the evolution dynamics of foam under extreme reservoir conditions such as high temperature and salinity. In this study, a performance evaluation experiment of foams generated by different types of surfactants was carried out by using the Waring-blender method. The foam stability characteristics were analyzed on the basis of foam volume, half-life of the liquid solution, and the foam comprehensive index and other related parameters. Based on the microscopic action mechanism of gas-liquid interface, the change pattern of foam performance with concentration, salinity and the coordinated action of core-shell particles were investigated. Both candidate surfactants exhibited good resistance to temperature and salinity. Among them, one surfactant demonstrated superior overall performance, with the foam comprehensive index reaching its peak at an optimal mass concentration of 0.5%. In high-salinity environments, the synergistic interaction between core-shell particles and surfactant molecules significantly enhances foam stability. In particular, the combination of this surfactant with core-shell particles at a mass fraction of 0.5% resulted in a notably higher foam comprehensive index, suggesting its strong application potential. This study quantitatively analyzes the synergistic stability effects of salinity, core-shell particles and surfactant, and reveals the synergistic stability mechanism of salt ion compression electric double layer and particle interface adsorption, providing important theoretical guidance for the development and application of deep reservoir foam flooding.

Document Type: Original article

Cited as: Xu, Z., Ding, G., Tao, L. Shi, W., Bai, J., Dang, F. Foam stabilization mechanism of core-shell particles: Insights from the gas-liquid interface theory. Capillarity, 2025, 16(1): 5-17. https://doi.org/10.46690/capi.2025.07.02


Keywords


Deep reservoir, high-temperature and high-salinity, foam performance, core-shell particle, interface effect

Full Text:

PDF

References


Abu Zaid, N. S. K., Johar, A., Nasser, M. S., et al. Synergistic effect of chemical and bio-based surfactants in stabilizing nanoemulsions. Geoenergy Science and Engineering, 2025, 247: 213663.

Akamine, T., Tosuai, T., Ramadhan, R., et al. Visualizing oil displacement by nanofluids at pore scale: A concentration-dependent nanofluid spreading induced by structural disjoining pressure. Capillarity, 2024, 12(1): 17-26.

Anu, M. A., Tomy, M., Gopi Krishnan, R., et al. Enhanced electrochemical properties of cobalt oxide nanoparticle electrode modified with low concentration of cationic surfactant. Journal of Electroanalytical Chemistry, 2024, 961: 118225.

Bello, A., Dorhjie, D. B., Ivanova, A., et al. A numerical feasibility study of CO2 foam for carbon utilization and storage in a depleted, high salinity, carbonate oil reservoir. Scientific Reports, 2024, 14(1): 20585.

Bersenev, E. A., Matthews, L., Rein, V., et al. Balance of hydrophobic and electrostatic interaction of polymers and surfactants: Case of anionic surfactant and hydrophobically modified polymer. Journal of Colloid and Interface Science, 2025, 693: 137572

Chen, J., Hou, L., Nan, J., et al. Prediction of critical micelle concentration (CMC) of surfactants based on structural differentiation using machine learning. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 703: 135276.

Dehdari, B., Parsaei, R., Riazi, M., et al. Dimensionless analysis of foam stability for application in enhanced oil recovery. Scientific Reports, 2024, 14(1): 29842.

Fujii, S. Foams/bubbles stabilized with polymer particles. Current Opinion in Colloid & Interface Science, 2024, 72: 101808.

Gbadamosi, A., Badmus, S. O., Haruna, K., et al. Surfactant applications in oil and gas industry: Efficiency, toxicity, and remediation techniques. Journal of Molecular Liquids, 2025, 427: 127440.

Joshi, D., Ramesh, D. N., Prakash, S., et al. Formulation and characterisation of polymer and nanoparticle-stabilized anionic surfactant foam for application in enhanced oil recovery. Surfaces and Interfaces, 2025, 56: 105615.

Li, K., Li, Y., Wang, W. Intelligent light-driven polystyrene foams for water purification and research into their functionality: Superhydrophobic, self-cleaning, oil-water separation, and photothermal conversion. Journal of Hazardous Materials, 2025, 489: 137611.

Li, Q., Wang, Y., Wei, B., et al. Imbibition oil recovery from tight reservoir cores using microemulsion: Experiment and simulation. Capillarity, 2024a, 10(2): 38-47.

Li, Y., Yang, Y., Dong, M. CO2 capillary trapping in layered sandstone dominated by inertial force and gravity. Capillarity, 2024b, 10(1): 22-28.

Lin, H., Zhou, Y., Jiang, B., et al. Effect on solution temperature on diffusion for water molecules and molecular characterization of lignite adsorbed ionic surfactants. Construction and Building Materials, 2025, 471: 140695.

Liu, Z., Ghatkesar, M. K., Sudhölter, E. J. R., et al. Understanding the cation-dependent surfactant adsorption on clay minerals in oil recovery. Energy & Fuels, 2019, 33(12): 12319-12329.

Lu, J., He, X., Li, B., et al. Super-wetting cu-mof-based foam for efficient oil/water separation and photothermal cleanup of crude oil. Separation and Purification Technology, 2025a, 353: 128483.

Lu, Y., Zhao, Y., Chen, Z., et al. Bioinspired superhydrophobic polysulfone foams with micro/nano hierarchical structures for highly efficient solar-assisted cleanup of viscous crude oil. Applied Surface Science, 2025b, 682: 161702.

Maestro, A., Rio, E., Drenckhan, W., et al. Foams stabilised by mixtures of nanoparticles and oppositely charged surfactants: Relationship between bubble shrinkage and foam coarsening. Soft Matter, 2014, 10(36): 6975-6983.

Ravazzano, C., Ferreira, G. A. The influence of bilayer fluidity on the stability of aqueous foams made from surfactant vesicle dispersions. Journal of Molecular Liquids, 2024, 397: 124136.

Seright, R. S., Wang, D. Polymer flooding: Current status and future directions. Petroleum Science, 2023, 20(2): 910921.

Shao, W., Yang, J., Wang, H., et al. Recent research progress on imbibition system of nanoparticle-surfactant dispersions. Capillarity, 2023, 8(2): 34-44.

Song, Z., Chen, S., Zhao, F., et al. Whole metagenome of injected and produced fluids reveal the heterogenetic characteristics of the microbial community in a waterflooded oil reservoir. Journal of Petroleum Science and Engineering, 2019, 176: 1198-1207.

Sun, J., Dai, L., Lv, K., et al. Recent advances in nanomaterials-stabilized pickering foam: Mechanism, classification, properties, and applications. Advances in Colloid and Interface Science, 2024a, 328: 103177.

Sun, Y., Jia, Z., Yu, B., et al. Research progress of nanoparticles enhanced carbon dioxide foam stability and assisted carbon dioxide storage: A review. Chemical Engineering Journal, 2024b, 495: 153177.

Tao, W., Jiang, B., Zheng, Y., et al. Molecular dynamics study on the effect of inorganic salts on the wettability of surfactants on bituminous coal: Sodium dodecyl sulfate and sodium chloride as representatives. Fuel, 2024, 359: 130397.

Tham, Y. Y., Molino, P. J., Higgins, M. J., et al. The study of deposition of wood extractives and model compound colloids onto chromium and cellulose surfaces using quartz crystal microbalance with dissipation (QCM-D). Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 491: 1-11.

Tran, T., Gonzalez Perdomo, M. E., Haghighi, M., et al. Effects of cationic and anionic surfactants on the stability, rheology and proppant suspension of nanoparticle-stabilized fracturing foams at elevated temperature. Geoenergy Science and Engineering, 2023, 228: 212041.

Vavra, E., Puerto, M., Biswal, S. L., et al. A systematic approach to alkaline-surfactant-foam flooding of heavy oil: Microfluidic assessment with a novel phase-behavior viscosity map. Scientific Reports, 2020, 10(1): 12930.

Wang, K., Xu, M., Zhou, B., et al. Study on the effects of inorganic salts and ionic surfactants on the wettability of coal based on the experimental and molecular dynamics investigations. Energy, 2024, 300: 131610.

Wang, T., Fan, H., Yang, W., et al. Stabilization mechanism of fly ash three-phase foam and its sealing capacity on fractured reservoirs. Fuel, 2020, 264: 116832.

Wang, Y., Wu, M., Hao, Y., et al. Surfactant-mediated transport of copper oxide nanoparticles in porous media: Effects of electrolytes, phosphate and organic matter. Chemical Engineering Research and Design, 2025, 217: 283-294.

Xu, H., Yu, Y., Weng, L., et al. Effect of structural design of core-shell particles and core-shell-shell particles on pvdf dielectric energy storage composite films. Journal of Materials Research and Technology, 2024, 31: 33203331.

Zhang, J., Niu, Q., Gao, Y., et al. The aggregation structure and rheological properties of catanionic surfactant mixtures and potential applications in fracturing fluids. Journal of Molecular Liquids, 2024, 407: 125118.

Zhang, L., Xie, J., Luo, X., et al. Enhanced hydrophobicity of shell-ligand-exchanged ZIF-8/melamine foam for excellent oil-water separation. Chemical Engineering Science, 2023, 273: 118663.

Zhang, Y., Liu, Q., Ye, H., et al. Nanoparticles as foam stabilizer: Mechanism, control parameters and application in foam flooding for enhanced oil recovery. Journal of Petroleum Science and Engineering, 2021, 202: 108561.

Zhang, Z., Qiao, M., Zhao, H., et al. Investigating the effect of hydrophilic SiO2 nanoparticles on foam stability using molecular dynamics simulation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2025, 712: 136429.

Zhou, L., Liu, Z., Wang, Y. Molecular insights: How counterions determine surfactant aggregation. Advances in Colloid and Interface Science, 2025, 341: 103484.

Zhou, Y., Tian, Y., Zhang, M. Technical development and application of supercritical CO2 foaming technology in pcl foam production. Scientific Reports, 2024, 14(1): 6825.


Refbacks

  • There are currently no refbacks.


Copyright (c) 2025 The Author(s)

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Copyright ©2018. All Rights Reserved