Effect of alcohol-treated CO2 on interfacial tension between CO2 and oil, and oil swelling
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Abstract
This paper investigates the extent to which alcohol-treated carbon dioxide (CO2 ), a mixture of alcohol and CO2 equilibrated at experimental pressure and temperature, can lead to greater interfacial tension reduction and greater oil swelling than can pure CO2 . Experimental measurements of interfacial tension and swelling behavior are made using a high-pressure, high-temperature visual cell at 70 °C. Two sets of fluid pairs are used: pure CO2 and oil, and alcohol-treated CO2 and oil. Two types of oil are used: a mixture of 35% hexane and 65% decane (C6 -C10 mixture), and pure decane (pure C10 ). Ethanol and methanol are used to prepare alcohol-treated CO2 . Numerical simulations are used to estimate a reduction in the minimum miscibility pressure when using alcohol-treated CO2 . Interfacial tension between alcohol-treated CO2 and oil is found to be 0.02 to 2.2 mN/m less than that between pure CO2 and oil. Simulation results suggest that alcohol-treated CO2 yields 0.2 to 1.2 MPa lower minimum miscibility pressure compared to pure CO2 . Alcohol-treated CO2 also is found to cause 6% to 43% more swelling of oil than does pure CO2 . Interfacial tension and swelling results suggest that alcohol-treated CO2 yields better miscibility with oil compared to pure CO2 .
Cited as: Saira, Yin, H., Le-Hussain, F. Effect of alcohol-treated CO2 on interfacial tension between CO2 and oil, and oil swelling. Advances in Geo-Energy Research, 2021, 5(4): 407-421, doi: 10.46690/ager.2021.04.06
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References
Ahmad, W., Vakili-Nezhaad, G., Al-Bemani, A. S., et al. Uniqueness, repeatability analysis and comparative evaluation of experimentally determined MMPs. Journal of Petroleum Science and Engineering, 2016, 147: 218-227.
Ahmed, T. Minimum miscibility pressure from eos. Paper SPE 137404 Presented at Canadian Unconventional Resources and International Petrolrum Conference, Calgary, Alberta, Canada, 19-21 October, 2000.
Aji, A. Q. M., Awang, M., Yusup, S. Fatty acid methyl ester from rubber seed oil as additives in reducing the minimum miscibility pressure of CO2 and crude oil. Journal of Applied Sciences, 2016, 16(11): 542-548.
Al Hinai, N. M., Myers, M. B., Dehghani, A. M., et al. Effects of oligomers dissolved in CO2 or associated gas on ift and miscibility pressure with a gas-light crude oil system. Journal of Petroleum Science and Engineering, 2019, 181: 106210.
Almobarak, M., Wu, Z., Myers, M. B., et al. Chemical-assisted minimum miscibility pressure reduction between oil and methane. Journal of Petroleum Science and Engineering, 2021, 196: 108094.
Al-Wahaibi, Y. M., Al-Hadrami, A. K. The influence of high permeability lenses on immiscible, first-and multi-contact miscible gas injection. Journal of Petroleum Science and Engineering, 2011, 77(3-4): 313-325.
Amooie, M. A., Soltanian, M. R., Moortgat, J. Hydrothermo-dynamic mixing of fluids across phases in porous media. Geophysical Research Letters, 2017, 44(8): 3624-3634.
Andreas, J. M., Hauser, E. A., Tucker, W. B. Boundary tension by pendant drops1. The Journal of Physical Chemistry, 2002, 42(8): 1001-1019.
Ayirala, S. C., Rao, D. N. Comparative evaluation of a new mmp determination technique. Paper SPE 99606 Presented at SPE/DOE Symposium on Improved Oil Recovery, Tulsa, Oklahoma, USA, 22-26 April, 2006.
Ayirala, S. C., Rao, D. N., Casteel, J. Comparison of minimum miscibility pressures determined from gas-oil interfacial tension measurements with equation of state calculations. Paper SPE 84187 Presented at SPE Annual Technical Conference and Exhibition, Denver, Colorado, 5-8 October, 2003.
Bagci, A. Immiscible CO2 flooding through horizontal wells. Energy Sources, Part A, 2007, 29(1): 85-95.
Bedrikovetsky, P. Wag displacements of oil-condensates accounting for hydrocarbon ganglia. Transport in Porous Media, 2003, 52(2): 229-266.
Bezanehtak, K., Combes, G. B., Dehghani, F., et al. Vapor-liquid equilibrium for binary systems of carbon dioxide + methanol, hydrogen + methanol, and hydrogen + carbon dioxide at high pressures. Journal of Chemical & Engineering Data, 2002, 47(2): 161-168.
Bikkina, P., Wan, J., Kim, Y., et al. Influence of wettability and permeability heterogeneity on miscible CO2 flooding efficiency. Fuel, 2016, 166: 219-226.
Chen, H. I., Chang, H. Y., Chen, P. H. High-pressure phase equilibria of carbon dioxide + 1-butanol, and carbon dioxide + water + 1-butanol systems. Journal of Chemical & Engineering Data, 2002, 47(4): 776-780.
Chen, H. I., Chen, P. H., Chang, H. Y. High-pressure vapor-liquid equilibria for CO2 + 2-butanol, CO2 + isobutanol, and CO2 + tert-butanol systems. Journal of Chemical & Engineering Data, 2003, 48(6): 1407-1412.
Chen, S., Gong, Z., Li, X., et al. Pore structure and heterogeneity of shale gas reservoirs and its effect on gas storage capacity in the qiongzhusi formation. Geoscience Frontiers, 2021, 12(6): 101244.
Choubineh, A., Helalizadeh, A., Wood, D. A. Estimation of minimum miscibility pressure of varied gas compositions and reservoir crude oil over a wide range of conditions using an artificial neural network model. Advances in Geo-Energy Research, 2019, 3(1): 52-66.
CMG-WinProp. CMG-Winprop PVT. Calgary, Canada CMG, 2018.
Dai, Z., Middleton, R., Viswanathan, H., et al. An integrated framework for optimizing CO2 sequestration and enhanced oil recovery. Environmental Science & Technology Letters, 2014, 1(1): 49-54.
Day, C. Y., Chang, C. J., Chen, C. Y. Phase equilibrium of ethanol + CO2 and acetone + CO2 at elevated pressures. Journal of Chemical & Engineering Data, 1996, 41(4): 839-843.
Dong, P., Liao, X., Chen, Z., et al. An improved method for predicting CO2 minimum miscibility pressure based on artificial neural network. Advances in Geo-Energy Research, 2019, 3(4): 355-364.
Emera, M. K., Sarma, H. K. Prediction of CO2 solubility in oil and the effects on the oil physical properties. Energy Sources, Part A, 2007, 29(13): 1233-1242.
Ershadnia, R., Wallace, C. D., Soltanian, M. R. CO2 geological sequestration in heterogeneous binary media: Effects of geological and operational conditions. Advances in Geo-Energy Research, 2020, 4(4): 392-405.
Green, D. W., Willhite, G. P. Enhanced Oil Recovery. Texas, USA, Henry L. Doherty Memorial Fund of AIME, Society of Petroleum Engineers, 1998.
Gu, Y., Zhang, S., She, Y. Effects of polymers as direct CO2 thickeners on the mutual interactions between a light crude oil and CO2 . Journal of Polymer Research, 2013, 20(2): 61.
Guo, B., Schechter, D. S. A simple and accurate method for determining low ift from pendant drop measurements. Paper SPE 37216 Presented at International Symposium on Oilfield Chemistry, Houston, Texas, 18-21 Febeuary, 1997.
Gupta, R. B., Shim, J. J. Solubility in Supercritical Carbon Dioxide. Boca Raton, USA, CRC Press, 2006.
Hrnčič, M. K., Markočič, E., Trupej, N., et al. Investigation of thermodynamic properties of the binary system polyethylene glycol/CO2 using new methods. The Journal of Supercritical Fluids, 2014, 87: 50-58.
Iglauer, S., Al-Yaseri, A. Improving basalt wettability to derisk CO2 geo-storage in basaltic formations. Advances in Geo-Energy Research, 2021, 5(3): 347-350.
Joung, S. N., Yoo, C. W., Shin, H. Y., et al. Measurements and correlation of high-pressure vle of binary CO2 -alcohol systems (methanol, ethanol, 2-methoxyethanol and 2-ethoxyethanol). Fluid Phase Equilibria, 2001, 185(1-2): 219-230.
Kamali, F., Hussain, F., Cinar, Y. A laboratory and numerical-simulation study of co-optimizing CO2 storage and CO2 enhanced oil recovery. SPE Journal, 2015, 20(6): 1227-1237.
Kathel, P., Mohanty, K. K. EOR in tight oil reservoirs through wettability alteration. Paper SPE 166281 Presented at SPE Annual Technical Conference and Exhibition, New Orleans, Louisiana, USA, 30 September-2 October, 2013.
Kravanja, G., Knez, Ž., Hrnčič, M. K. Density, interfacial tension, and viscosity of polyethylene glycol 6000 and supercritical CO2 . The Journal of Supercritical Fluids, 2018a, 139: 72-79.
Kravanja, G., Knez, Ž., Hrnčič, M. K. The effect of argon contamination on interfacial tension, diffusion coefficients and storage capacity in carbon sequestration processes. International Journal of Greenhouse Gas Control, 2018b, 71: 142-154.
Kuang, N., Yang, S., Yuan, Z., et al. Study on oil and gas amphiphilic surfactants promoting the miscibility of CO2 and crude oil. ACS Omega, 2021, 6(41): 27170-27182.
Lake, L.W. Enhanced oil recovery. United States, 1989.
Li, F., Yang, S., Chen, H., et al. An improved method to study CO2 -oil relative permeability under miscible conditions. Journal of Petroleum Exploration Production Technology, 2015, 5(1): 45-53.
Li, J., Rodrigues, M., Matos, H. A., et al. Vle of carbon dioxide/ethanol/water: Applications to volume expansion evaluation and water removal efficiency. Industrial & Engineering Chemistry Research, 2005, 44(17): 6751-6759.
Li, P., Yi, L., Liu, X., et al. Screening and simulation of offshore CO2 -EOR and storage: A case study for the HZ21-1 oilfield in the Pearl River Mouth Basin, Northern South China Sea. International Journal of Greenhouse Gas Control, 2019, 86: 66-81.
Li, Q., Wang, Y., Wang, X., et al. An application of thickener to increase viscosity of liquid CO2 and the assessment of the reservoir geological damage and CO2 utilization. Energy Sources, Part A, 2019, 41(3): 368-377.
Li, Q., Zhang, Z., Zhong, C., et al. Solubility of solid solutes in supercritical carbon dioxide with and without cosolvents. Fluid Phase Equilibria, 2003, 207(1-2): 183-192.
Liu, B., Fu, X., Li, Z. Impacts of CO2 -brine-rock interaction on sealing efficiency of sand caprock: A case study of shihezi formation in ordos basin. Advances in Geo-Energy Research, 2018, 2(4): 380-392.
Luo, H., Zhang, Y., Fan, W., et al. Effects of non-ionic surfactant (CiPO j ) on the interfacial tension behavior between CO2 and crude oil. Energy & Fuels, 2018, 32(6): 6708-6712.
Moradi, B., Awang, M., Bashir, A., et al. Effects of alcohols on interfacial tension between carbon dioxide and crude oil at elevated pressures and temperature. Journal of Petroleum Science and Engineering, 2014, 121: 103-109.
NIST Chemistry Webbook. Washington, D.C. National Institute of Standards and Technology, 1997.
Orr, F. M. Theory of Gas Injection Processes. Copenhagen, Denmark, Tie-Line Publications, 2007.
Orr, F. M., Jessen, K. An analysis of the vanishing interfacial tension technique for determination of minimum miscibility pressure. Fluid Phase Equilibria, 2007, 255(2): 99-109.
Rao, D. N. A new technique of vanishing interfacial tension for miscibility determination. Fluid Phase Equilibria, 1997, 139(1): 311-324.
Reid, R. C., Sherwood, T. K., Prausnitz, J. M. The properties of gases and liquids. United States, 1977.
Ren, J., Wang, Y., Feng, D., et al. CO2 migration and distribution in multiscale-heterogeneous deep saline aquifers. Advances in Geo-Energy Research, 2021, 5(3): 333-346.
Renner, R. Tracking the dirty byproducts of a world trying to stay clean. American Association for the Advancement of Science, 2004, 306(5703): 1887.
Rommerskirchen, R., Bilgili, H., Fischer, J., et al. Impact of miscibility enhancing additives on the flooding scheme in CO2 EOR processes. Paper SPE 190288 Presented at SPE Improved Oil Recovery Conference, Tulsa, Oklahoma, USA, 14-18 April, 2018.
Rommerskirchen, R., Nijssen, P., Bilgili, H., et al. Reducing the miscibility pressure in gas injection oil recovery processes. Paper SPE 183389 Presented at Abu Dhabi International Petroleum Exhibition & Conference, Abu Dhabi, UAE, 7-10 November, 2016.
Rudyk, S., Hussain, S., Spirov, P. Supercritical extraction of crude oil by methanol-and ethanol-modified carbon dioxide. The Journal of Supercritical Fluids, 2013, 78: 63-69.
Rudyk, S., Spirov, P., Hussain, S. Effect of co-solvents on SC-CO2 extraction of crude oil by consistency test. The Journal of Supercritical Fluids, 2014, 91: 15-23.
Saini, D., Rao, D. N. Experimental determination of minimum miscibility pressure (mmp) by gas/oil ift measurements for a gas injection EOR project. Paper SPE 132389 Presented at the SPE Western Regional Meeting, Anaheim, California, USA, 27-29 May, 2010.
Saira, Ajoma, E., Le-Hussain, F. A laboratory investigation of the effect of ethanol-treated carbon dioxide injection on oil recovery and carbon dioxide storage. SPE Journal, 2021, 26(5): 3119-3135.
Saira, Janna, F., Le-Hussain, F. Effectiveness of modified CO2 injection at improving oil recovery and CO2 storage-review and simulations. Energy Reports, 2020, 6: 1922-1941.
Schneider, C. A., Rasband, W. S., Eliceiri, K. W. NIH Image to ImageJ: 25 years of image analysis. Nature Methods, 2012, 9(7): 671-675.
Sequeira, D. S., Ayirala, S. C., Rao, D. N. Reservoir condition measurements of compositional effects on gas-oil interfacial tension and miscibility. Paper SPE 113333 Presented at SPE Symposium on improved Oil Recovery, Tulsa, Oklahoma, USA, 20-23 April, 2008.
Shang, Q., Xia, S., Cui, G., et al. Experiment and correlation of the equilibrium interfacial tension for paraffin + CO2 modified with ethanol. The Journal of Chemical Thermodynamics, 2018, 116: 206-212.
Thomas, F. B., Holowach, N., Zhou, X., et al. Miscible or near-miscible gas injection, which is better? Paper SPE 27811 Presented at SPE/DOE improved Oil Recovery Symposium, Tulsa, Oklahoma, 17-20 April, 1994.
Tsivintzelis, I., Missopolinou, D., Kalogiannis, K., et al. Phase compositions and saturated densities for the binary systems of carbon dioxide with ethanol and dichloromethane. Fluid Phase Equilibria, 2004, 224(1): 89-96.
Tunio, S. Q., Tunio, A. H., Ghirano, N. A., et al. Comparison of different enhanced oil recovery techniques for better oil productivity. International Journal of Applied Science and Technology, 2011, 1(5): 143-153.
Yang, Z., Li, M., Peng, B., et al. Dispersion property of CO2 in oil. 1. Volume expansion of CO2 + alkane at near critical and supercritical condition of CO2 . Journal of Chemical & Engineering Data, 2012, 57(3): 882-889.
Yang, Z., Wu, W., Dong, Z., et al. Reducing the minimum miscibility pressure of CO2 and crude oil using alcohols. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 568: 105-112.
Zhang, C., Xi, L., Wu, P., et al. A novel system for reducing CO2 -crude oil minimum miscibility pressure with CO2 -soluble surfactants. Fuel, 2020a, 281: 118690.
Zhang, L., Wang, Y., Miao, X., et al. Geochemistry in geologic CO2 utilization and storage: A brief review. Advances in Geo-Energy Research, 2019, 3(3): 304-313.
Zhang, X., Ge, J., Kamali, F., et al. Wettability of sandstone rocks and their mineral components during CO2 injection in aquifers: Implications for fines migration. Journal of Natural Gas Science and Engineering, 2020b, 73: 103050.
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